Chiral superconductors are unconventional superconducting states that break time reversal symmetry spontaneously and typically feature Cooper pairing at non-zero angular momentum. Such states may host Majorana fermions and provide an important platform for topological physics research and fault-tolerant quantum computing. Despite intensive search, chiral superconductivity has remained elusive so far. Here we report the discovery of robust unconventional superconductivity in rhombohedral tetra- and penta-layer graphene in the absence of moiré superlattice effects. Spontaneous time-reversal-symmetry-breaking (TRSB) due to electron’s orbital motion is found, and several observations indicate the chiral nature of these superconducting states. Our observations establish a pure carbon material for the study of topological superconductivity, and pave the way to explore Majorana modes and topological quantum computing.
Crossed Andreev reflection is a non-local transport phenomenon that creates and detects Cooper pair correlations between distant locations. It is also the basis of Cooper pair splitting to generate remote entanglement. Although crossed Andreev reflection has been extensively studied in semiconductors proximity-coupled to a superconductor, observing it in a topological insulator has been very difficult. In this work, we report the observation of this effect in a proximitized topological insulator nanowire. We perform local and non-local conductance spectroscopy on mesoscopic devices in which superconducting niobium and metallic contacts are connected to a bulk-insulating nanowire. In our local conductance measurements we detect a hard gap and the appearance of Andreev bound states that can reach zero bias. We also occasionally observe a negative non-local conductance when sweeping the chemical potential, providing evidence of crossed Andreev reflection. This signal is detected even over length scales much longer than the expected superconducting coherence length of either niobium or the proximitized nanowire. We suggest that this long-range effect is due to the intricate role of disorder in proximitized nanowires.
Magnetic impurities on superconductors present a viable platform for building advanced applications in quantum technologies. In this work, we show the manipulation of magnetic states in the radical molecule 4,5,9,10-tetrabromo-1,3,6,8-tetraazapyrene on a Pb(111) superconducting surface using low-temperature scanning tunneling microscopy. Tunneling spectra reveal Yu-Shiba-Rusinov (YSR) states near the Fermi energy in isolated molecules. The presence of a second TBTAP molecule allows tuning of the YSR state position by altering the relative distance and can induce splitting of the YSR states for certain orientations. The construction of molecular chains up to pentamers shows periodic arrangements of charged and neutral molecules, with even-numbered chains forming a charged dimer structure at one end. Information can be encoded in these chains by switching the dimer position. These findings elucidate interactions between molecular assemblies and superconducting substrates, paving the way for advanced quantum-state engineering.
Using surface coordination chemistry with pyrene-4,5,9,10-tetraone (PTO) precursors as ligands, Jung-Ching Liu and coworkers have demonstrated the synthesis of an iron-based spin chain on Ag(111) and Pb(111). Low temperature tunneling spectroscopy (white spectrum) shows low-energy spin excitations (orange arrows) from coordinated Fe atoms with high S = 2 spin-state.
Flat bands in Kagome graphene might host strong electron correlations and frustrated magnetism upon electronic doping. However, the porous nature of Kagome graphene opens a semiconducting gap due to quantum confinement, preventing its fine-tuning by electrostatic gates. Here we induce zero-energy states into a semiconducting Kagome graphene by inserting π- radicals at selected locations. We utilize the on-surface reaction of tribromotrioxoazatriangulene molecules to synthesize carbonyl-functionalized Kagome graphene on Au(111), thereafter modified in situ by exposure to atomic hydrogen. Atomic force microscopy and tunneling spectroscopy unveil the stepwise chemical transformation of the carbonyl groups into radicals, which creates local magnetic defects of spin state S = 1/2 and zero-energy states as confirmed by density functional theory.